I was watching some Enterprise reruns and saw an episode featuring Orions, that made the point that Vulcans are immune to Orion pheromones.
So I went looking to see if any other species are immune, and found numerous references saying that other species are immune, but not which ones.
Considering the Klingons probably wouldn't want Orion women taking over, they would probably have some of said species around that are immune? Gorn or Lethean, maybe?
Or perhaps there's another way they'd make sure they weren't under the influence?
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