Well, I don't have the Pulp Ray Gun to be able to directly compare their numbers atm (if one is based on TGM and the other on AR then they should be pretty similar, though). But iirc the Ray Gun uses Unified Theory or MSA for a dmg boost, while the Ice Rifle takes 3x Chill and potentially ice objects (which Chill itself can create). The Ray Gun is prob less rng-based, but the Ice Rifle could do more burst if it shatters an ice object. Hard Frost will also boost the rifle's dmg, while Chest Beam's Burn Through is prob the best bet to debuff for the ray gun. You may want to pick between them based on the supporting powers and their theme or mechanics, since they can be quite different.
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- Be safe and have fun, champs - for science!