I've put Delegated Devastation III on my eng and sci BOffs as they are pseudo-healers and the buff to everyone else is good. Hammer and Anvil III is also on those same guys since it's another team-wide boost. Finally, I put Hammer and Anvil II on my other two BOffs which are tacs. Haven't messed with much else though, and decided not to put anything on my actual toon.
Strategic Analysis and Return Fire are probably the nicer abilities to use.. I'm not sure if it's really worth giving up your Captain's kit module slots when there are exclusive lockbox/reputation/event modules to consider though.
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My character Tsin'xing